![]() “Squid Squad” is a very simple word to pronounce. As a result, a new term, Squad of Squid, is being considered. ![]() The gathering of squids was previously known as a shoal. A Squid Squad sounds like a better idea! Isn’t that so? What’s the point of using words like shoal or school?ĭon’t they have a right to expect more? Of course, it must have a name that better describes its collective activity. Likewise, the most intriguing aspect of these events is deciding what to call them for the Squid’s posse. Continue reading to learn more! Three Squid Group Secret NamesĪmazing things happen when marine organisms join together. They have around 300 species, some of which have ten arms. Their eyes are enormous, and they have long bodies with two tentacles and eight limbs. The Squid most closely resembles an octopus. This petition is still active and in need of more signatories. A petition has been started to rename the squid group the Squad instead of the Shoal. The term “squad” has not yet been officially approved. Conspiracy and audience are two more collective words for this aquatic species. What do you name a group of Squid?Ī group of Squid is known as a squad, school, or shoal. Surprisingly, the names of their groups are more interesting than the animals themselves. What’s fascinating about these underwater creatures is how frequently they congregate. Squid is a must-have for everyone who appreciates the critters of the deep. Let me tell you about Cephalopods, which are the ancestors of Squid. What kind of sea creature existed before fish? Have you ever considered it? There were dinosaurs on the planet before mammals. A shoal of Squid is a school of Squid that communicates using their skin in a highly quick and colorful manner. Jellyfish can create massive swarms when conditions are favorable, causing damage to fishing gear by overflowing fishing nets and clogging the cooling systems of power and desalination plants that draw their water from the sea.
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You can select from a list of pre-configured Shortcuts or create new ones using an editor. Shortcuts for Mac lets you save time by removing steps when performing essential tasks. One of the best features to arrive on iPhone and iPad in the past decade is now on macOS. And because it's an Apple world, Focus works best when you sync your groups across all of your devices. Under this scenario, you could create a work-based Focus group that turns on/off whenever you're at one of the locations between certain hours of the day.Īdding this type of flexibility to receiving notifications saves time and makes it easier to concentrate on the tasks at hand. ![]() Throw in the occasional trip to the local Starbucks where you also sometimes work, and there are three work-related locations. For example, let's say you work at home two days a week and in an office the other three. At first glance, location-based options seem much less critical on Mac until you realize just how valuable they can become if you move sporadically between various locations. ![]() You can also have them kick on whenever you're at a particular location (the local gym) or using a specific app or game. The beginning and end of each Focus Group aren't just time-based. Otherwise, these notifications are kept quiet until the group session expires.Īdding this type of flexibility to receiving notifications saves time and makes it easier to concentrate on the tasks at hand. You can create new groups for fitness, game playing, or anything else in just a few steps.įor each Focus group, you decide who's allowed to contact you and which apps can send you alerts during the specified times. The most apparent Focus groups are those for work hours, driving, and sleep time. Everything here is controlled by Focus groups, which you can create manually or pick from the canned options. With Screen Time, Apple made it easier for parents to track and restrict what their kids were doing online while keeping track of their online activities and getting a gentle nudge when it was time to take a break.įocus expands on this by making it possible to restrict notifications and communication, depending on the time of day or what we're doing. For Apple, this has meant introducing a Screen Time tool across its many platforms. ![]() The big tech companies have spent the last few years making it easier for us to unplug. Todd’s clients are among the most successful musicians, actors, writers, directors, sports personalities and high net worth individuals in the entertainment industry. He has served as the firm’s CEO for over 20 years. In 1987, Todd relocated to Los Angeles, where he joined GR&F. He gained significant experience in international business operations through two years spent in the London offices of C&L. ![]() After college, Todd joined the international accounting firm Coopers & Lybrand (“C&L”), where he spent the following nine years. ![]() in accounting and is a member of the American Institute of Certified Public Accountants. Tyson Gay is flying back to Lexington on Sunday.Īn autopsy will be conducted on Trinity Gay Monday morning.Todd graduated from the University of California Berkeley with a B.A. Sending our thoughts & prayers to & his loved ones as they mourn the tragic & senseless loss of his daughter, Trinity.- USATF October 16, 2016 can't even imagine what you must be going thru. As you head to church pray for His daughter was killed last night.- Lauryn Williams October 16, bro want to send my condolences. Sad news for a member of our Family this morning. The Arkansas Razorback athletic family sends its condolences to and his family during this difficult time.- Arkansas Track & Field October 16, 2016Īthletes and Olympians also expressed their condolences on social media. Our hearts are broken this morning over the loss of Trinity to this tragic and senseless act of violence.- Fayette County Public Schools October 16, 2016 #StoptheViolence #LLTrinity- BSHS Track And Field October 16, 2016 Local schools and track teams expressed their grief over Trinity’s death. The school system has activated a Crisis Team, which will be at Lafayette High School on Monday to offer counseling and support to students and staff. “Please join us in keeping the Gay family close in thought and prayer and supporting the students, staff and families at Lafayette High during this unspeakably difficult time.” “Our hearts are broken this morning over the loss of Trinity to this tragic and senseless act of violence,” Fayette County Schools Superintendent Manny Caulk said in a statement. “In that sense, I am trying to balance my time so I can watch her career and I can finish up my career,” Gay said.Ĭondolences poured in from friends and associates of both father and daughter. “It was pretty amazing to watch her run and compete and still keep her spirits up high when she didn’t win.” “I’m at a point where I want to be involved in more of her sports,” he said. She attended Lafayette High School in Lexington and was a sprinter on the school’s track team, according to CNN affiliate WKYT.ĭuring a 2012 interview with CNN’s “Aiming for Gold” show, Gay spoke of his daughter’s athletic aspirations and his desire to nurture them. Gay received a one-year ban from the U.S. He won a silver medal for the 4x100-meter relay at the 2012 Olympic games in London, but had to return it when he tested positive for a prohibited anabolic steroid at the U.S. Gay won gold medals in the 100-meter, 200-meter and 4x100-meter relay at the 2007 world championships in Osaka, Japan. Gay ran the 100-meter in 9.69 seconds in 2009, matching Bolt’s gold-winning effort at the Beijing Olympics in 2008. Gay, a native of Lexington, is the second fastest man to run the 100-meter in history, behind Usain Bolt. Police are still looking for the second vehicle, which witnesses described as a dark sports car with tinted windows. Another man who was questioned by police has not been charged, according to a police statement. He has been charged with wanton endangerment and possession of a firearm by a convicted felon. Police believe he was in the parking lot when the shooting occurred and fired multiple shots. Authorities arrested 21-year-old Dvonta Middlebrooks on Sunday afternoon. Lexington police located one of the two cars involved in the shootout – a gray Dodge Charger – within a few hours of the incident, and detained two people for questioning. Gay was taken to UK Hospital in a private vehicle, where she later died, police said. ![]() The scene in Lexington, KY where the deadly shooting of Trinity Gay occurred. ![]() In other words, the reaction is highly selective for one stereoisomer over the other. Here, notice that we observe only the “anti” product and none of the “syn” product. When we treat an alkene with a halogen such as Br 2, (often in a halogenated solvent such as CH 2Cl 2 or CCl 4) we obtain the following product using 1,2-dimethylcyclohexene.Īgain, pay attention to the dashes and wedges. Addition Of Bromine (Br 2) To Alkenes Is Stereoselective, Giving “Anti” Addition Stereochemistry Any mechanism we propose for this reaction will have to be able to explain why we end up with a mixture of these two products. They exist in roughly equal amounts in this example, but the point is that the mechanism does not selectively deliver either the syn or the anti product. So a feature of this reaction is that it produces a mixture of syn and anti products. Our term for this relationship is “ syn“. Our term for this relationship is “ anti” *. In the product on the right, the Br and H are on the same side of the ring (and therefore have added to the same face of the alkene). In other words, H and Br added to opposite faces of the starting alkene. In the product on the left, the Br and H are on opposite sides of the ring. The “connectivity” of each molecule is the same, but they differ in their orientation in space! Notice how in the left hand product, the H and Br are on opposite sides of the ring, whereas in the right hand product, they are on the same side? These two compounds are not the same – they are “ stereoisomers“. “Later” is now! Examine the placement of the H and the Br that are added. In the previous post I said to ignore all the dashes and wedges, because we’d deal with them later. Addition Of H-Br To Alkenes Is Not Stereoselective, And Gives A Roughly Equal Mixture Of “Syn” And “Anti” Productsįirst example: let’s take a cyclic molecule like 1,2-dimethylcyclohexene and treat it with hydrobromic acid (HBr). Later on, we will use this evidence to make hypotheses about how these reactions work. ![]() Without prior knowledge, it isn’t possible to predict from first principles how they proceed – those who discovered these reactions in the late 1800’s and early 1900’s didn’t know what we know now. Remember, these are results from experiment. (The carbocation pathway, the “3-membered ring” pathway, and the “concerted” pathway) However, later we’ll see that each of these reactions is characteristic of a particular “family” of reactivity for addition reactions. Those three reactions we’ll look at today are addition of HBr, bromination with Br 2, and hydrogenation with Pd-C and H 2. A Collection Of Observations That Nobody Predicted Ahead Of Time Until They Did The Experiment Summary: Stereoselectivity In Alkene Addition Reactionsġ.Hydrogenation Of Alkenes With Pd-C And H 2 Is Selective For Addition Stereochemistry.Addition Of Bromine To Alkenes Is Stereoseletvie, Giving “Anti” Addition Stereochemistry.Addition Of H-Br To Alkenes Is Not Stereoselective, And Gives A Roughly Equal Mixture Of “Syn” And “Anti” Products.A Collection of Observations On Reaction Alkene Addition Stereochemistry That Nobody Predicted Ahead Of Time.We’re going to look at three key reactions of alkenes and see how they each demonstrate a different pattern of stereochemistry in addition reactions. This post is about the second key theme in addition reactions of alkenes: stereochemistry. In the last post on alkene addition reactions, we discussed one of the two key themes to look for in addition reactions: regiochemistry (in other words – what is the favored direction in which the pi-bond breaks). Stereoselectivity In Alkene Addition Reactions: “Syn” vs “Anti” ![]() ![]() This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.įunding: This work was supported by the Swiss National Foundation grants 135754, 141898, 132815 and NCCR Structural Biology. Received: Accepted: SeptemPublished: October 30, 2013Ĭopyright: © 2013 Sun et al. Raghava, CSIR-Institute of Microbial Technology, India (2013) AAscan, PCRdesign and MutantChecker: A Suite of Programs for Primer Design and Sequence Analysis for High-Throughput Scanning Mutagenesis. Ĭitation: Sun D, Ostermaier MK, Heydenreich FM, Mayer D, Jaussi R, Standfuss J, et al. The software is distributed under GPLv3 licence and is available at. We hope that the open-source nature of our software and ready availability of freeware tools used for its development will facilitate its adaptation and further development. We have used AAscan software to design primers to make over 700 mutants, with a success rate of over 80%. We also describe additional software tools which are used to analyse a large number of sequencing results for the presence of desired mutations, as well as related software to design primers for ligation independent cloning. Here we present an open-source multi-platform software AAscan developed to design primers for this task according to a set of empirical rules such as melting temperature, overall length, length of overlap regions, and presence of GC clamps at the 3’ end, for any desired substitution. One of the time-consuming tasks encountered in application of this technique is the design of primers for site-directed mutagenesis. Scanning mutagenesis is a powerful protein engineering technique used to study protein structure-function relationship, map binding sites and design more stable proteins or proteins with altered properties. ![]() ![]()
![]() ![]() David Archy's's review score also factors in its popularity, which is in the mid-range compared to competing. Pouch With more than 6,800 reviews on Amazon and a near-perfect rating, David Archy. David Archy offers 0 total features such as, and. 2 inch Phone Bag Waist Bag Pouch Leather Belt Bag Purse 280 reviews. Unique dual pouch design to protect mens intimate area, a new era of mens underwear has come. After having been patented in America and Europe, a new brand Separatec was born. Based on these factors and 19 David Archy reviews, David Archy earns an overall score of 4.0 out of 5.0 points. Is David Archy and Separatec the same 2018 Dual Pouch Underwear Dual pouch underwear was firstly designed by David Archy and known as David Archy Doctor series. Knoji reviews and ranks and other men's underwear brands based on how many features each offers and based on a 5-star rating scale. Classic undershirt: Wider range of size fits the body shape well providing more comfort to wear. Knoji editors and the Knoji shopper community have reviewed David Archy and compared it against 0 top brands, reviewing David Archy based on product and store features such as ethically-sourced products, and. Ratings for DAVID ARCHY (CPR Score) 9.5 View on Amazon Customer Reviews Features Ultra softness: The combed cotton with better toughness and great weaving structure brings a soft touch. Knoji has 19 David Archy reviews and ratings as of October 22, 2022. ![]() Does each brand offer fair trade products? Is each brand fair trade certified?Īre each brand products made in the USA? Does each brand manufacture their products in the United States?Īre products sold at each brand cruelty free? Does each brand sell cruelty-free products?ĭoes each brand use eco-friendly materials? Does each brand use recyclable materials? Are you allowed a certain number of days off per year without having to pay, or are you expected to pay any time you are out of town? Also, find out how much lead time the sitter needs to know about your vacation if you will not be paying during those days. In addition, you will need to know what happens when your family takes a vacation. How far in advance you will know when she is taking time off so that you can make alternate arrangements? What are your vacation policies? Find out whether the in-home daycare provider takes a vacation every year.In addition to knowing when you will need care, also be sure to know whether you are expected to pay the in-home daycare provider for holidays when she is open but your child is not attending. “It’s frustrating because we have to go through it every year,” she explains. Jessica, a mom of 2, says that her sitter takes off all the major holidays, but when they ask about other federal holidays such as Martin Luther King, Jr. What holidays do you take off? Make sure you are both on the same page about what holidays you will not need care, as well as what holidays the childcare provider will not be available. ![]() If the parents decide not to, the sitter does not charge them. Between her 4 kids and my 4 kids, it started getting ridiculous sometimes how often I had to stay home or try to find a backup.” She says her current babysitter, on the other hand, quarantines her own children upstairs if they are home sick and allows the parents to decide whether or not to bring their own kids that day. One fellow mom shared with me, “My first provider had 4 kids of her own and would cancel on me at the last minute if any of them stayed home sick. In addition, if the in-home daycare provider has children of her own, find out what happens if they are sick. If you decide to keep your sick child home with you, will you be responsible for paying for that time? What are your policies around child illness? You will need to know whether your sitter is willing to watch your own sick child on occasion.“I have heard of other people who send their child to an in-home daycare led by one person, and when they got sick, unfortunately, they couldn’t bring them and didn’t have a backup plan.” “It was super nice if one of them happened to have an emergency or get sick, we still were able to maintain bringing our daughter there,” she recalls. Sara, mom of 2, says there were two to three people on staff at her in-home daycare. Some in-home daycare providers have backup plans in place. If they were too sick to work, we would have to stay home or find alternate care for the kids. If you are sick or have an emergency, what is the plan you have in place to take care of my child? The two in-home daycare providers I used over the course of 6 years did not provide backup care options for my children.What is the childcare provider’s policy if you are late for the pickup? Some in-home daycare providers do not watch children over school breaks, including summer, so this would be another important issue to bring up if you would need care during those times. What hours are you open? It will be important to know how early or late you are able to drop your child off or pick her up.Questions to Ask In-Home Daycare about Availability What should I look for in a home daycare?.Additional Important Questions to Ask In-Home Daycare Providers.Questions about the In-Home Daycare Provider’s Credentials.Finance-Related Questions to Ask In-Home Daycare.Communication between the Parent and In-Home Daycare Provider.Handling Challenges and Special Circumstances. ![]()
The Miller School Wins Designation as Center for AIDS Research - 2012 Researchers at the University of Miami Miller School of Medicine identify a new strategy for attacking esophageal adenocarcinoma (EAC), one of the most deadly forms of cancer. Collaborative Study Finds New Approach for Treating Esophageal Cancer - 2014 Bascom Palmer Researchers Discover Protein that Leads to Glaucoma - 2105Ī team of Bascom Palmer Eye Institute researchers discovers that the protein cochlin, most recognized in concentrated levels within the inner ear, is present in the eye and has an effect on glaucoma. Julio Frenk, M.D., M.P.H., Ph.D., a physician, former Dean at Harvard University and the former Minister of Health for Mexico,becomes the sixth president of the University of Miami. The Miller School of Medicine and UHealth Welcome President Julio Frenk - 2015 ![]() The Miller School of Medicine establishes the Institute for Bioethics and Health Policy to provide guidance and support in the shaping of institutional and public policy. Institute for Bioethics and Health Policy Opens - 2016 This innovative program offers comprehensive training in ophthalmic translational research, problem-based learning, management and a skill set available only at Bascom Palmer. Bascom Palmer Eye Institute Launches Dynamic New Master’s Degree - 2016īascom Palmer Eye Institute launches the world’s first Master’s degree in Vision Science and Investigative Ophthalmology (MVSIO). The University of Miami creates the Department of Interventional Radiology, demonstrating its leadership in this versatile therapy. University of Miami Creates Pioneering Department of Interventional Radiology - 2016 to incorporate this first-of-its-kind virtual reality simulation technology in its teaching program. The Bascom Palmer Eye Institute and Gordon Center for Research in Medical Education announces partnership with HelpMeSee, a non-profit humanitarian organization and is the first medical center in the U.S. University of Miami First to Train Medical Students Using HelpMeSee Eye Surgery Simulator - 2018 The team was the first to develop a mouse model of a hematologic malignancy by using CRISPR to create a specific chromosomal translocation in transplantable blood stem cells. Researchers pioneer a new use for CRISPR, the genomic editing tool. Novel Use of CRISPR for Cancer Research - 2018 ![]() New HIV Treatment Strategy Provides Long-term Viral Suppression - 2019Ī Miller School research team discovers a new approach to preventing and treating HIV infection in a preclinical model.
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